I might have seen more of these when I was little, but I don't remember them so I won't count those.
The first one that really made an impression on me was License to Kill... just because it was SO violent!! Bond locks a guy in a compartment full of maggots, guys get killed by sharks and eels. a dude gets his head burst in a decompression chamber, a guy gets pulled into a cocaine crusher, not to mention all the guys getting shot or blown up.